Biased Tracer Diffusion in Hard - Core Lattice Gases : Some Notes on the Validity of the Einstein Relation

نویسندگان

  • G. Oshanin
  • O. Bénichou
  • S. F. Burlatsky
  • M. Moreau
چکیده

In this presentation we overview some recent results on biased tracer diffusion in lattice gases. We consider both models in which the density of lattice gas particles is explicitly conserved and situations in which the lattice gas particles undergo continuous exchanges with a reservoir, which case is appropriate, e.g. to adsorbed monolayers in contact with the vapor phase. For all these models we determine, in some cases exactly and in other ones-using a certain decoupling approximation, the mean displacement of a tracer particle (TP) driven by a constant external force in a dynamical background formed by the lattice gas particles whose transition rates are symmetric. Evaluating the TP mean displacement explicitly we are able to define the TP mobility, which allows us to demonstrate that the Einstein relation between the TP mobility and the diffusivity generally holds, despite the fact that in some cases diffusion is anomalous. For models treated within the framework of the decoupling approximation, our analytical results are confirmed by Monte Carlo simulations. Per-turbance of the lattice gas particles distribution due to the presence of a biased TP and the form of the particle density profiles are also discussed.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Tracer Diffusion in Hard - Core Lattice Gases : Some Notes on the Validity of the Einstein Relation

In this presentation we overview some recent results on biased tracer diffusion in lattice gases. We consider both models in which the gas particles density is explicitly conserved and situations in which the lattice gas particles undergo continuous exchanges with a reservoir, which case is appropriate, e.g., to adsorbed monolayers in contact with the vapor phase. For all these models we determ...

متن کامل

Ultraslow vacancy-mediated tracer diffusion in two dimensions: the Einstein relation verified.

We study the dynamics of a charged tracer particle (TP) on a two-dimensional lattice, all sites of which except one (a vacancy) are filled with identical neutral, hard-core particles. The particles move randomly by exchanging their positions with the vacancy, subject to the hard-core exclusion. In the case when the charged TP experiences a bias due to external electric field E (which favors its...

متن کامل

Glassy Relaxation and Breakdown of the Stokes-Einstein Rela- tion in the Two Dimensional Lattice Coulomb Gas of Fractional Charges

– We present Monte Carlo simulation results on the equilibrium relaxation of the two dimensional lattice Coulomb gas with fractional charges, which exhibits a close analogy to the primary relaxation of fragile supercooled liquids. Single particle and collective relaxation dynamics show that the Stokes-Einstein relation is violated at low temperatures, which can be characterized by a fractional ...

متن کامل

Force - velocity relation and density profiles for biased diffusion in an adsorbed monolayer

In this paper, which completes our earlier short publication [Phys. Rev. Lett. 84, 511 (2000)], we study dynamics of a hard-core tracer particle (TP) performing a biased random walk in an adsorbed monolayer, composed of mobile hard-core particles undergoing continuous exchanges with a vapor phase. In terms of an approximate approach, based on the decoupling of the third-order correlation functi...

متن کامل

Diffusion processes and memory effects

We report the results of the numerical estimation of statistical memory effects in diffusion for two various systems: Lennard-Jones fluids and the model of the Brownian particle in a one-dimensional harmonic lattice. We have found the relation between the diffusion coefficient and the non-Markovity parameter, which is linear for the Lennard-Jones systems in liquid state. The relation between th...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2002